Smoky quartz is a macrocrystalline variety of the mineral Quartz (SiO2). Quartz is the most abundant single mineral on earth. It makes up about 12% of the earth's crust, occurring in a wide variety of igneous, metamorphic and sedimentary rocks.
Quartz
varieties are commonly separated into two groups based on the size of
the individual grains or crystals; macrocrystalline quartz in which
individual crystals are distinguishable with the naked eye, and cryptocrystalline
quartz in which the individual crystals are too small to be easily distinguishable
under the light microscope.
Some of the macrocrystalline quartz varieties are: Amethyst, Ametrine, Cat's-eye Quartz, Citrine, Phantom Quartz, Rock Crystal, Rose Quartz, Rutilated Quartz and Smoky Quartz.
Blue
Aventurine Quartz and Green Aventurine Quartz are actually quartzites
(a rock, not a mineral) composed essentially of interlocking macrocrystalline
quartz grains with disseminated grains of other color imparting minerals.
The cryptocrystalline varieties of quartz may be separated into two types; fibrous and microgranular. Chalcedony is the general term applied to the fibrous cryptocrystalline varieties. Agate is an example of a fibrous cryptocystalline banded chalcedony variety of quartz. Carnelian, Chrysoprase and bloodstone are other chalcedony varieties.
Chert is the general term applied to the granular cryptocrystalline varieties of quartz, of which flint and Jasper are examples.
PHYSICAL PROPERTIES
Smoky Quartz chemical composition: SiO2
Class: tectosilicate
Crystal system: Hexagonal-Rhombohedral; 32 (trigonal-trapezohedral)
Crystal habit: Macroscopic crystals commonly occur as horizontally striated
hexagonal prisms terminated by a combination of positive and negative
rhombohedrons forming six sided pyramids. Prism faces and/or rhombohedral
terminations may be lacking, poorly developed or predominant resulting
in diverse possible crystal habits. Trigonal tapezohedral faces can
occur in the upper right or left of alternating prism faces identifying
right or left handed crystals, respectively.
Twinning: Dauphine twin with c the twin axis, Brazil
twin with {1120} the twin plane, Japanese twin is rare with {1122} the
twin plane.
Specific gravity: 2.65
Index of refraction: 1.54-1.55
Birefringence: maximum of 0.009
Pleochroism: distinct
Hardness: 7
Color: brown to gray to black
Luster: vitreous
Transparency: transparent
Cleavage: none
Fracture: conchoidal
Streak: white

Smoky
quartz or Smokey quartz, also known as Cairngorm or Cairngormstone is
a brown to black variety of quartz caused through the natural (or artificial)
irradiation of aluminium-containing rock crystal. A very dark brown
to black opaque variety is known as morion.