Citrine
is any quartz crystal or cluster that is yellow or orange in color.
Although often cut as a gemstone, citrine is actually somewhat rare
in nature. Most citrines on the market have been heat treated. Specimens
of low grade, inexpensive amethyst or smoky quartz are often cooked
at high temperatures to produce the more profitable orange yellow
citrine. Citrines whose colors have been produced by artificial means
tend to have much more of an orange or reddish caste than those found
in nature, which are usually a pale yellow. 
Much
of the natural citrine may have started out as amethyst but heat from
nearby magmatic bodies may have caused the change to citrine. Citrine
made by heating amethyst may be returned to a purple color by bombarding
it with beta radiation. Interestingly, a popular gemstone on the market
is a mixture of half amethyst and half citrine and is given the name
ametrine, made by heating an amethyst until it turns into citrine,
then
irradiating
a part of the resulting crystal or gemstone to convert that portion
back to amethyst.
Unfortunately
for citrine it is often confused with the more expensive orange-yellow
topaz and is at times sold as topaz by unscrupulous dealers. This
practice has soured many potential citrine fanciers who see citrine
as a fake topaz and not as a legitimate gemstone.
Citrine
is only one of several quartz varieties. Other varieties that form
macroscopic (large enough to see) crystals are as follows: